The First Organometallic Version of Polyaniline in ...



Title The First Organometallic Version of Polyaniline in its Emaraldine Form
Author(s) Karl Gagnon, Shawkat M. Aly, Daniel Fortin, Alaa S. Abd-El-Aziz, Pierre D. Harvey
Journal Journal of Inorganic and Organometallic Polymers and Materials,
Date 2009
Volume 19
Issue 1
Start page 28
End page 34
Abstract The reaction of bis(para-ethynylbenzene)-2,3,5,6-tetramethoxyquinone diimine and bis(para-ethynylbenzene)-2,3,5,6-tetramethoxyquinone diamine and trans-Pt(PEt3)2Cl2 in a 1:1:2 ratio in the presence of CuI and iPrNH2 generates the polydispersed material poly(bis(para-ethynylbenzene)-2,3,5,6-tetramethoxy-quinone diimine)-trans-bis(triethyl-phosphine)platinum(II)-(bis(para-ethynylbenzene)-2,3,5, 6-tetramethoxyquinone diamine)-trans-bis(triethylphosphine)platinum(II). Based on the luminescence decay traces, the distribution of the diimine and diamine residues is statistic.
DOI 10.1007/s10904-009-9256-x

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