Opening of oxabicyclo[3.2.1]octenes with ...



Title Opening of oxabicyclo[3.2.1]octenes with organolithium reagents. A route to cyclic and acyclic compounds with high stereocontrol.
Author(s) Mark Lautens, Alaa S. Abd-El-Aziz, Alan Lough
Journal Journal of Organic Chemistry,
Date 1990
Volume 55
Issue 19
Start page 5305
End page 5306
Abstract A range of oxabicyclo[3.2.l]octenes has been found to undergo opening when treated with organolithium reagents. Up to five stereocenters are created in two steps. Oxidative cleavage leads to a stereocontrolled synthesis of polysubstituted cycloheptanediols.
DOI 10.1021/jo00306a002

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