Opening of oxabicyclo[3.2.1]octenes with ...
|Title||Opening of oxabicyclo[3.2.1]octenes with organolithium reagents. A route to cyclic and acyclic compounds with high stereocontrol.|
|Author(s)||Mark Lautens, Alaa S. Abd-El-Aziz, Alan Lough|
|Journal||Journal of Organic Chemistry,|
|Abstract||A range of oxabicyclo[3.2.l]octenes has been found to undergo opening when treated with organolithium reagents. Up to five stereocenters are created in two steps. Oxidative cleavage leads to a stereocontrolled synthesis of polysubstituted cycloheptanediols.|
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