Preparation and ring-opening metathesis ...
|Title||Preparation and ring-opening metathesis polymerizations of 5-siloxydeltacyclene and deltacyclene using the Schrock molybdenum alkylidene catalyst.|
|Author(s)||M. Lautens, C. Crudden, A. Abd-El-Aziz, T. Wada|
|Journal||Section Title: Chemistry of Synthetic High Polymers, Macromolecules|
|Abstract||The living ring-opening metathesis polymns. of deltacyclene (I) and 5-(tert-butyldimethylsiloxy)deltacyclene (II) in presence of the Schrock catalyst Mo(=CHCMe2Ph)[=N-2,6-(iso-Pr)2Ph](O-tert-Bu)2 were described. II was prepd. by first epoxidizing I, then treating this epoxide with a Lewis acid in presence of thiophenol. The rearrangement that ensued placed an alc. at C-5 position and trapped the nucleophile at C-8 position, allowing the reintroduction of the double bond by oxidn. of the sulfide followed by a thermal elimination. The polymns. of I and II were done neat or in soln. II polymer was substantially more sol. in org. solvents than I polymer. [on SciFinder(R)]|
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