Substituent effects in the iron 2p and carbon 1s ...
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| Title | Substituent effects in the iron 2p and carbon 1s edge near-edge x-ray absorption fine structure spectroscopy of metal arene complexes and polymers. |
| Author(s) | E. Otero, P. Shipman, A. Abd-El-Aziz, S. Urquhart |
| Journal | Section Title: Organometallic and Organometalloidal Compounds, Organometallics |
| Date | 2009 |
| Volume | 28 |
| Issue | 7 |
| Start page | 2160 |
| End page | 2172 |
| Abstract | The authors have examd. the electronic structure of iron arene monomers and polymers by near-edge x-ray absorption fine structure spectroscopy. Electron-donating or -withdrawing substituents have a measurable effect on some features in the NEXAFS spectra of these species. However, more significant changes are obsd. that arise from strong π*-conjugation between the arene ligand (benzene or cyclopentadienyl) and substituents bonded to this ligand. Spectral features obsd. in the Fe 2p and C 1s NEXAFS spectra were assigned with the aid of EHMO and DFT calcns. [on SciFinder(R)] |
| DOI | 10.1021/om800769t |
| ISSN | 0276-7333 |
Using APA 6th Edition citation style.
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