Potassium fluoride-celite as a heterogeneous ...
|Title||Potassium fluoride-celite as a heterogeneous catalyst in arylation of 1,3-dicarbonyl compounds by arenes activated by complexation with the cyclopentadienyl iron moiety.|
|Author(s)||R. Sutherland, A. Abd-El-Aziz, A. Piorko, C. Lee|
|Journal||Section Title: Organometallic and Organometalloidal Compounds, Synthetic Communications|
|Abstract||RCOCH2COR1 (R, R1 = Me, Ph, OEt) are arylated with o-R2C6H4R3Fe+cp PF6- (R2 = H, R3 = Cl, NO2; R2 = R3 = Cl; cp = cyclopentadienyl) in THF-DMSO contg. KF on celite to give 73-80% o-R2C6H4CH(COR)COR1Fe+cp PF6- (same R-R2) in a nucleophilic arom. substitution reaction. [on SciFinder(R)]|
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