Conductivity anisotropy of ...

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Title Conductivity anisotropy of polyphosphazene-montmorillonite composite electrolytes
Author(s) J. C. Hutchison, Rabin Bissessur, D. F. Shriver
Journal Chemistry of Materials
Date 1996
Volume 8
Issue 8
Start page 1597
End page 1599
Abstract The conductivity of an ordered polyphosphazene Na+-montmorillonite composite has been measured perpendicular (sigma(para)) and parallel (sigma(perp)) to the montmorillonite layers, and the sigma(para)/sigma(perp) is about 100. The temperature dependence of the conductivity is consistent with a coupling between long-range Na+ movement and high-amplitude segmental motion of the polymer. The anisotropy is attributed to greater tortuosity of the Na+ diffusion perpendicular to the montmorillonite layers.

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