Synthesis of alpha-amino-acids by addition of ...



Title Synthesis of alpha-amino-acids by addition of putative azido radicals to alpha-methoxy acrylonitriles derived from aldehydes and ketones
Author(s) D. L. J. Clive, Nola Etkin
Journal Tetrahedron Letters
Date 1994
Volume 35
Issue 16
Start page 2459
End page 2462
Abstract alpha-Methoxy acrylonitriles, available from aldehydes and ketones, react with sodium azide in the presence of eerie ammonium nitrate to give azido nitrates; from these compounds, alpha-amino acids are obtained by sequential treatment with sodium acetate in acetic acid and then methanolic potassium carbonate, followed by hydrogenation.

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