Reactivity of fluorenylideneketene towards amines. A ...
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Citation
| Title | Reactivity of fluorenylideneketene towards amines. A laser photolysis study with ultraviolet and infrared detection. |
| Author(s) | N. deLucas, J. NettoFerreira, J. Andraos, J. Lusztyk, B. Wagner, J. Scaiano |
| Journal | Tetrahedron Letters |
| Date | 1997 |
| Volume | 38 |
| Issue | 29 |
| Start page | 5147 |
| End page | 5150 |
| Abstract | The ketene derived from diazoquinone 5 can be readily detected by laser photolysis techniques with IR detection and its behavior agrees with that observed with more conventional UV-visible detection. The ketene reacts with amines (e.g. k similar to 7 x 10(7) M-1 s(-1) for diethylamine) to give ylides (yielding amides as final products) that absorb in the 300-340 nm and 1670-1680 cm(-1) regions. (C) 1997 Elsevier Science Ltd. |
| ISSN | 0040-4039 |
Using APA 6th Edition citation style.
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