A nonspectroscopic method to determine the ...
|Title||A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine: Carbene, diazo and rearrangement in excited state|
|Author(s)||T. Wakahara, Y. Niino, T. Kato, Y. Maeda, T. Akasaka, Michael T. H. Liu, K. Kobayashi, S. Nagase|
|Journal||Journal of the American Chemical Society|
|Abstract||C-60 acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the photolysis of 3-chloro-3-isopropyldiazirine and 3-chloro-3-chloromethyldiazirine. The carbene adds to C-60 to form methanofullerene, whereas the diazo compound adds to C-60 to form fulleroid. The olefin product arises as a result of the rearrangement in the excited state.|
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