Laser flash photolysis studies on intra- and ...

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Title Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes
Author(s) Michael T. H. Liu, R. Bonneau
Journal Journal of the American Chemical Society
Date 1996
Volume 118
Issue 34
Start page 8098
End page 8101
Abstract Laser flash photolysis studies on alpha-methylbenzylchlorodiazirine, n-propylchlorodiazirine, and isopropylchlorodiazirine have been carried out at low temperatures, ranging from 170 to 230 K. The present results, together with those previously obtained with benzylchlorodiazirine and methylchlorodiazirine, provide a direct measurement of the ''by-stander effect'' of alkyl substituents on the C atom in the alpha position of the carbene center. Intermolecular reactions of alpha-methylbenzylchlorocarbene and tetramelhylethylene in isooctane and methylcyclohexane have been measured but this reaction is shown to be too slow to measure by LFP in highly viscous decalin solvent.

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