Kinetics of intramolecular and intermolecular ...

Description

Citation

Title Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene
Author(s) Michael T. H. Liu, R. G. Chapman, R. Bonneau
Journal Journal of Photochemistry and Photobiology A-Chemistry
Date 1992
Volume 63
Issue 1
Start page 115
End page 118
Abstract Photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gives E- and Z-beta-chlorostyrenes and cyclopropane. Relative rate studies show that the styrenes to cyclopropane ratio increases with increasing diazirine concentration. This permits the determination of the ratio k(D)/k(i) = 8 where k(D) is the rate constant for the reaction of carbene with diazirine and k(i) is the rate constant for the 1,2-hydrogen atom shift of carbene. Laser flash photolysis yields the first absolute rate constant for the reaction of a chlorocarbene with diazirine and a value of 7.7 for k(D)/k(i).

Using APA 6th Edition citation style.

[Page generation failure. The bibliography processor requires a browser with Javascript enabled.]

Times viewed: 203

Adding this citation to "My List" will allow you to export this citation in other styles.