Cyclobutenbriarein A, the first diterpene with a ...
|Title||Cyclobutenbriarein A, the first diterpene with a tricyclo[18.104.22.168(3,6)]tetradec-4-ene ring system isolated from the Gorgonian Briareum asbestinum|
|Author(s)||N. Gonzalez, J. Rodriguez, Russell G. Kerr, C. Jimenez|
|Journal||The Journal of Organic Chemistry|
|Abstract||Cyclobutenbriarein A (2), a novel class of C20-rearranged diterpene briarane possessing an unprecedented tricyclo[22.214.171.124(3,6)]tetradec-4-ene ring system was isolated, along with five new briarane diterpenoids (1 and 3-6), from the organic extracts of the Bahamian gorgonian Briareum asbestinum. The structures of these secondary metabolites were established on the basis of extensive NMR studies and accurate mass measurements (HRFABMS).|
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