Pyrrole syntheses based on titanium-catalyzed ...



Title Pyrrole syntheses based on titanium-catalyzed hydroamination of diynes
Author(s) Balaji Ramanathan, A. J. Keith, D. Armstrong, A. L. Odom
Journal Organic Letters
Date 2004
Volume 6
Issue 17
Start page 2957
End page 2960
Abstract Titanium-catalyzed hydroamination of 1,4- and 1,5-diynes by primary amines leads to imino-alkynes that undergo in situ 5-endo dig and 5-exo dig cyclization reactions, respectively. The products are 1,2,5-trisubsituted pyrroles accessed directly from readily available diyne starting materials.
DOI 10.1021/ol0489088

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