Activation volumes for peroxodisulfate oxidation of ...



Title Activation volumes for peroxodisulfate oxidation of cobalt(iii), iron(ii) and nickel(ii) complexes
Author(s) J. Benko, O. Vollarova, S. Alshehri, J. Burgess, Robert I. Haines
Journal Transition Metal Chemistry
Date 1993
Volume 18
Issue 6
Start page 551
End page 554
Abstract Dependences of rate constants on pressure (in aqueous solution up to 1.25 kbar) are reported for peroxodisulphate oxidation of hexacyanoferrate(TI), tris(2,2'-bipyridyl)iron(II), tris(l,10-phenanthroline)iron(II), bis(l,4,7-triazacyclononane)nickel(II) and bis(l,2-ethanediamine)cysteinatocobalt(III) and its thioglycollato-analogue, and for periodate oxidation of the two last-named complexes. Derived activation volumes are reported and discussed in terms of intrinsic and solvational contributions. Rate laws and pressure effects on reactivity are reported for the reaction of peroxodisulphate with pentacyanoferrates(II) containing N-alkylpyrazinium ligands.

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