Solvent effects on discrimination of the ...



Title Solvent effects on discrimination of the dissociative substitution of pentacyano(ligand)ferrate(II) complexes in alcohol-water mixtures
Author(s) M. J. Blandamer, J. Burgess, Robert I. Haines
Journal Journal of the Chemical Society, Dalton Transactions
Date 1978
Issue 3
Start page 244
End page 247
Abstract Solvent effects on the discriminatory properties of the transient [Fe(CN)5]3? intermediate in the dissociative (D) substitution at the complex ions [Fe(CN)5L]3?(L = 3- or 4-cyanopyridine) are described. The solvents employed are methanol?, ethanol?, and t-butyl alcohol?water mixtures; in each case the incoming group is cyanide ion.
DOI 10.1039/DT9780000244
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