Kinetics of reactions of Schiff-base complexes of ...

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Title Kinetics of reactions of Schiff-base complexes of iron (II). Part 6. The preparation and kinetics of reactions of multidentate ligand complexes
Author(s) M. J. Blandamer, J. Burgess, Robert I. Haines, F. M. Mekhail, P. Askalini
Journal Journal of the Chemical Society, Dalton Transactions
Date 1978
Volume
Issue 8
Start page 1001
End page 1008
Abstract Preparations of iron(II) complexes of bi-, tri-, quadri-, quinque-, and sexi-dentate Schiff bases are reported. The Schiff-base ligands are derived from pyridine-2-carbaldehyde, phenyl 2-pyridyl ketone, pyridine-2,6-dicarb-aldehyde. or 2,6-diacetylpyridine, and appropriate amines. All these complexes aquate in acid solution, and react with cyanide to give ternary iron(II)?cyanide?Schiff-base complexes. The kinetics of aquation of several of these Schiff-base complexes, and the kinetics of cyanide attack at all the complexes, are described, and reactivities are compared with those for analogous reactions of other iron(II) di-imine complexes. Solvent effects on the re-activity with cyanide of one of the complexes of the sexidentate Schiff bases in a range of binary aqueous mixtures are discussed.
DOI 10.1039/DT9780001001
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