Michael Liu

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Name	Michael T. H. Liu
Position	Emeritus Faculty
Email	liu@upei.ca
Department(s)	Chemistry
Phone	(902) 566-0314
Website	http://research.upei.ca/profile/michaelliu

Michael T. H. Liu

Biography

Title: Professor Emeritus

Education: B.Sc., Saint Dunstan’s University; M.A., Saint Francis Xavier University; Ph.D., University of Ottawa

Recent Citations

Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine
Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct
Isolation and characterization of carbene derivatives of LaC82(Cs)
Metal Atoms Collinear with the Spiro Carbon of 6,6-Open Adducts, M2@C80(Ad) (M = La and Ce, Ad = Adamantylidene)
Nanorods of endohedral metallofullerene derivative

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Research Interests

Carbenes
1,2-Hydrogen Migration
laser flash photolysis
azomethine ylide
1,5-cylization, synthesis of biologically active nitrogen-containing heterocycles
C60 carbene adducts

Other Scholars in Chemistry

Citations

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	Title	Author(s)
	A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine	Wakahara, T.; Niino, Y.; Kato, T.; Maeda, Y.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
	Photolysis of diazirines in the presence of C-60	Akasaka, T.; Liu, Michael T. H.; Niino, Y.; Maeda, Y.; Wakahara, T.; Okamura, M.; Kobayashi, K.; Nagase, S.
	Structural determination of metallofuIlerene SC3C82 revisited	Liduka, Y.; Wakahara, T.; Nakahodo, T.; Tsuchiya, T.; Sakuraba, A.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Kato, T.; Liu, Michael T. H.; Mizorogi, N.; Kobayashi, K.; Nagase, S.
	Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienes	Bonneau, R.; Romashin, Y. N.; Liu, Michael T. H.
	Quantum yield of formation of diazo compounds from the photolysis of diazirines	Bonneau, R.; Liu, Michael T. H.
	Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivative	Iiduka, Y.; Wakahara, T.; Nakajima, K.; Nakahodo, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
	Isolation and characterization of a carbene derivative of La@C-82	Maeda, Y.; Matsunaga, Y.; Wakahara, T.; Takahashi, S.; Tsuchiya, T.; Ishitsuka, M. O.; Hasegawa, T.; Akasaka, T.; Liu, Michael T. H.; Kokura, K.; Horn, E.; Yoza, K.; Kato, T.; Okubo, S.; Kobayashi, K.; Nagase, S.; Yamamoto, K.
	Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atoms	Romashin, Y. N.; Liu, Michael T. H.; Nijjar, S. S.; Attanasi, O. A.
	The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienes	Romashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
	S-heterocyclic carbene with a disilane backbone	Nikawa, H.; Nakahodo, T.; Tsuchiya, T.; Wakahara, T.; Rahman, G. M. A.; Akasaka, T.; Maeda, Y.; Liu, Michael T. H.; Meguro, A.; Kyushin, S.; Matsumoto, H.; Mizorogi, N.; Nagase, S.
	1,2-Hydrogen migration in carbenes and mimicking processes	Bonneau, R.; Liu, Michael T. H.
	Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct	Akasaka, Takeshi; Kono, Takayoshi; Takematsu, Yuji; Nikawa, Hidefumi; Nakahodo, Tsukasa; Wakahara, Takatsugu; Ishitsuka, Midori O.; Tsuchiya, Takahiro; Maeda, Yutaka; Liu, Michael T. H.; Yoza, Kenji; Kato, Tatsuhisa; Yamamoto, Kazunori; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
	Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine	Ishitsuka, Midori O.; Enoki, Haruka; Tsuchiya, Takahiro; Slanina, Zdenek; Mizorogi, Naomi; Nagase, Shigeru; Liu, Michael T. H.; Akasaka, Takeshi
	Isolation and characterization of carbene derivatives of LaC82(Cs)	Akasaka, Takeshi; Kono, Takayoshi; Matsunaga, Yoichiro; Wakahara, Takatsugu; Nakahodo, Tsukasa; Ishitsuka, Midori; Maeda, Yutaka; Tsuchiya, Takahiro; Kato, Tatsuhias; Liu, Michael T.H.; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
	Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe technique	Ishitsuka, M. O.; Enoki, H.; Nikawa, H.; Wakahara, T.; Tsuchiya, T.; Akasaka, T.; Liu, Michael T. H.
	A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique	Ishitsuka, M. O.; Niino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
	Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbene	Bonneau, R.; Collado, D.; Dalibart, M.; Liu, Michael T. H.
	Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridine	Bonneau, R.; Collado, D.; Liu, Michael T. H.
	Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates	Romashin, Y. N.; Liu, Michael T. H.; Hill, B. T.; Platz, M. S.
	Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide	Romashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
	Kinetic and spectroscopic properties of carbene-diazirine ylides	Bonneau, R.; Liu, Michael T. H.
	New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenes	Romashin, Y. N.; Liu, Michael T. H.; Ma, W.; Moss, R. A.
	Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirines	Shustov, G. V.; Liu, Michael T. H.; Houk, K. N.
	A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopy	Werstiuk, N. H.; Muchall, H. M.; Ma, J. G.; Liu, Michael T. H.
	On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systems	Shustov, G. V.; Liu, Michael T. H.
	Gas phase protonation of diazirines	Matsumoto, T.; Kobayashi, S.; Mishima, M.; Shustov, G. V.; Liu, Michael T. H.
	Benzylchlorocarbene	Merrer, D. C.; Moss, R. A.; Liu, Michael T. H.; Banks, J. T.; Ingold, K. U.
	Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical study	Shustov, G. V.; Liu, Michael T. H.; Rauk, A.
	1, 2-H shift in benzylchlorocarbene	Liu, Michael T. H.; Bonneau, R.; Wierlacher, S.; Sander, W.
	Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysis	Liu, Michael T. H.; Romashin, Y. N.; Bonneau, R.
	Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a Carbene	Liu, Michael T. H.
	Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol	Liu, Michael T. H.; Romashin, Y. N.; Venkatachalam, T. K.
	Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullerene	Liu, Michael T. H.; Romashin, Y. N.; Kubota, M.; Ohashi, M.
	Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirine	Kwiatkowski, W.; Bakshi, P. K.; Cameron, T. S.; Liu, Michael T. H.
	Thermolysis and photolysis of arylchlorodiazirines in allyl bromide	Bonneau, R.; Grobys, M.; Liu, Michael T. H.; Himori, M.; Fukushima, K.; Ibata, T.
	Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirine	Liu, Michael T. H.; Chateauneuf, J. E.
	Rearrangement of an ammonium ylide: mechanisms and kinetic parameters	Bonneau, R.; Reuter, I.; Liu, Michael T. H.
	Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridine	Bonneau, R.; Romashin, Y. N.; Liu, Michael T. H.; Macpherson, S. E.
	First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene	Liu, Michael T. H.
	Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixes	Wierlacher, S.; Sander, W.; Liu, Michael T. H.
	Cycloaddition of arylchlorocarbenes using ultrasound	Bertram, A. K.; Liu, Michael T. H.
	Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysis	Bonneau, R.; Liu, Michael T. H.
	Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbene	Liu, Michael T. H.; Chateauneuf, J. E.
	Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenes	Liu, Michael T. H.; Bonneau, R.
	Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirine	Liu, Michael T. H.; Bonneau, R.
	Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine	Cameron, T. S.; Bakshi, P. K.; Borecka, B.; Liu, Michael T. H.
	Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene	Liu, Michael T. H.; Chapman, R. G.; Bonneau, R.
	Carboxylation of carbenes in low-temperature matrixes	Wierlacher, S.; Sander, W.; Liu, Michael T. H.
	Spectroscopic detection of ammonium ylides from arylchlorocarbenes and amines	Bonneau, R.; Liu, Michael T. H.
	Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chloride	Liu, Michael T. H.; Chateauneuf, J. E.
	Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbene	Chateauneuf, J. E.; Liu, Michael T. H.
	Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formation	Chateauneuf, J. E.; Liu, Michael T. H.
	Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene	Liu, Michael T. H.; Murray, S.; Zhu, J. H.
	Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygen	Liu, Michael T. H.; Bonneau, R.; Jefford, C. W.
	The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acid	Stevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
	Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenes	Liu, Michael T. H.; Bonneau, R.
	A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloaddition	Bonneau, R.; Liu, Michael T. H.
	Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopy	Liu, Michael T. H.; Bonneau, R.
	Rates for 1, 2-migration in alkylchlorocarbenes	Bonneau, R.; Liu, Michael T. H.; Rayez, M. T.
	Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes	Liu, Michael T. H.; Bonneau, R.
	Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene	Jackson, J. E.; Soundararajan, N.; White, W.; Liu, Michael T. H.; Bonneau, R.; Platz, M. S.
	Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlation	Bonneau, R.; Liu, Michael T. H.; Lapouvade, R.
	Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity	Bonneau, R.; Liu, Michael T. H.; Suresh, R. V.
	Spectroscopy and dynamics of para-nitrophenylchlorocarbene	Bonneau, R.; Liu, Michael T. H.
	Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins	Jackson, J. E.; Soundararajan, N.; Platz, M. S.; Doyle, M. P.; Liu, Michael T. H.
	The barrier for 1, 2-hydrogen shift in dialkyl carbenes	Stevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
	Benzylchlorocarbene: a new ambiphile	Liu, Michael T. H.; Suresh, R. V.; Soundararajan, N.; Vessey, E. G.
	Studies on benzylchlorocarbene	Liu, Michael T. H.; Suresh, R. V.
	Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene	Doyle, M. P.; Taunton, J.; Oon, S. M.; Liu, Michael T. H.; Soundararajan, N.; Platz, M. S.; Jackson, J. E.
	Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities	Soundararajan, N.; Platz, M. S.; Jackson, J. E.; Doyle, M. P.; Oon, S. M.; Liu, Michael T. H.; Anand, S. M.
	Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis	Jackson, J. E.; Soundararajan, N.; Platz, M. S.; Liu, Michael T. H.
	Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirine	Linden, A.; Cameron, T. S.; Liu, Michael T. H.; Anand, S. M.
	Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanol	Liu, Michael T. H.; Subramanian, R.
	Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formation	Ibata, T.; Toyoda, J.; Liu, Michael T. H.
	Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complex	Liu, Michael T. H.; Soundararajan, N.; Paike, N.; Subramanian, R.
	Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrile	Liu, Michael T. H.; Paike, N.
	Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate	Liu, Michael T. H.; Soundararajan, N.; Anand, S. M.; Ibata, T.
	Catalysis of olefin isomerization by tight ion pairs	Liu, Michael T. H.; Doyle, M. P.; Loh, K. L.; Anand, S. M.
	Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetone	Ibata, T.; Liu, Michael T. H.; Toyoda, J.
	Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate	Doyle, M. P.; Loh, K. L.; Nishioka, L. I.; Mcvickar, M. B.; Liu, Michael T. H.
	Substituent and temperature effects on the reactions of benzylchlorocarbene with alcohol	Liu, Michael T. H.; Subramanian, R.
	Electron spin resonance studies of diazirine anion radicals	Elson, C. M.; Liu, Michael T. H.; Mailer, C.
	Reaction of phenylchlorocarbene in oxygen-doped matrices	Ganzer, G. A.; Sheridan, R. S.; Liu, Michael T. H.
	on the thermal decomposition of diazirines	Liu, Michael T. H.; Tencer, M.; Stevens, I. D. R.
	Energy barrier for 1,2-hydrogen migration in benzylbromocarbene	Liu, Michael T. H.; Subramanian, R.
	Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolane	Liu, Michael T. H.; Kokosi, J.
	Reaction of benzylchlorocarbene with hydrogen chloride	Liu, Michael T. H.; Subramanian, R.
	Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene	Liu, Michael T. H.
	Kinetics of the oxidation of cyclohexene by thallium(II1) acetate	Loucks, L. F.; Liu, Michael T. H.; Durant, D. K.
	Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reaction	Liu, Michael T. H.; Subramanian, R.
	The order of CH3CHO decomposition - comment	Liu, Michael T. H.
	Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanol	Tomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
	Termolecular trapping of benzylchlorocarbene by methanol	Liu, Michael T. H.; Subramanian, R.
	Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenes	Tomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
	Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirine	Liu, Michael T. H.; Chishti, N. H.; Tencer, M.; Tomioka, H.; Izawa, Y.
	Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkene	Tomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
	Electronic effect on 1,2-hydrogen shift in chlorocarbenes	Liu, Michael T. H.; Tencer, M.
	Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylidene	Sugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
	Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxide	Sugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
	Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acid	Griller, D.; Liu, Michael T. H.; Montgomery, C. R.; Scaiano, J. C.; Wong, P. C.
	Hydrogen bonding in alcohols: its effect on the carbene insertion reaction	Griller, D.; Liu, Michael T. H.; Scaiano, J. C.
	The thermolysis and photolysis of diazirines	Liu, Michael T. H.
	Dihydrosilaanthracenylidene and dihydroanthracenylidene	Sekiguchi, A.; Ando, W.; Sugawara, T.; Iwamura, H.; Liu, Michael T. H.
	Electrochemical behavior of diazirines	Elson, C. M.; Liu, Michael T. H.
	Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazene	Vaughan, K.; Liu, Michael T. H.
	Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimine	Liu, Michael T. H.; Ibata, T.
	Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirine	Liu, Michael T. H.; Palmer, G. E.; Chishti, N. H.
	Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impact	Liu, Michael T. H.; Tanaka, T.; Hirotsu, T.; Fukui, K.; Fujita, I.; Kuwata, K.
	Synthesis of 3-chloro-3-methyl-d3-diazirine	Liu, Michael T. H.; Chishti, N. H.; Burkholder, C. D.; Jones, W. E.; Wasson, J. S.
	MNDO calculations on diazirines	Burkholder, D.; Jones, W. E.; Ling, K. W.; Wasson, J. S.; Liu, Michael T. H.
	Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms	Burkholder, C. D.; Jones, W. E.; Wasson, J. S.; Liu, Michael T. H.
	Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decomposition	Loucks, L. F.; Liu, Michael T. H.; Hooper, D. G.
	Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathways	Liu, Michael T. H.; Yamamoto, I.
	Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes	Liu, Michael T. H.; Bonneau, R.
	Rearrangement of alkylchlorocarbenes	Bonneau, R.; Liu, Michael T. H.; Kim, K. C.; Goodman, J. L.
	A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridyl	Bonneau, R.; Liu, Michael T. H.
	Metal Atoms Collinear with the Spiro Carbon of 6,6-Open Adducts, M2@C80(Ad) (M = La and Ce, Ad = Adamantylidene)	Yamada, M.; Someya, C.; Wakahara, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
	Effect of substituents on the thermal decomposition of diazirines	Liu, Michael T. H.; Choe, Y. K.; Kimura, M.; Kobayashi, K.; Nagase, S.; Wakahara, T.; Niino, Y.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.
	Adamantylidene revisited	Bonneau, R.; Hellrung, B.; Liu, Michael T. H.; Wirz, J.
	Nanorods of endohedral metallofullerene derivative	Tsuchiya, Takahiro; Kumashiro, Ryotaro; Tanigaki, Katsumi; Matsunaga, Yoichiro; Ishitsuka, Midori O.; Wakahara, Takatsugu; Maeda, Yutaka; Takano, Yuta; Aoyagi, Motoki; Akasaka, Takeshi; Liu, Michael T. H.; Kato, Tatsuhisa; Suenaga, Kazutomo; Jeong, Jong S.; Iijima, Sumio; Kimura, Fumiko; Kimura, Tsunehisa; Nagasev, Shigeru
	Photochemical decomposition of pyrazoline produced in the reaction of C60 with Diazoadamantane	Niino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.
	Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirine	Liu, Michael T. H.
	Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis	Bonneau, R.; Liu, Michael T. H.; Subramanian, R.; Linkletter, Barry A.; Stevens, I. D. R.

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Title	Times viewed	Last viewed
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine - ir:ir-batch6-1372	84	11:18:58 2013-06-19
Photolysis of diazirines in the presence of C-60 - ir:ir-batch6-1374	80	19:13:29 2013-06-18
Structural determination of metallofuIlerene SC3C82 revisited - ir:ir-batch6-1364	71	11:37:48 2013-06-13
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienes - ir:ir-batch6-1377	79	01:47:39 2013-06-18
Quantum yield of formation of diazo compounds from the photolysis of diazirines - ir:ir-batch6-1388	73	08:58:48 2013-06-14
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivative - ir:ir-batch6-5547	80	09:13:03 2013-06-19
Isolation and characterization of a carbene derivative of La@C-82 - ir:ir-batch6-1367	71	22:34:10 2013-06-17
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atoms - ir:ir-batch6-1375	85	23:38:47 2013-06-18
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienes - ir:ir-batch6-1380	89	14:18:18 2013-06-16
S-heterocyclic carbene with a disilane backbone - ir:ir-batch6-1363	78	09:33:27 2013-06-16
1,2-Hydrogen migration in carbenes and mimicking processes - ir:ir-batch6-1486	83	09:08:25 2013-06-14
Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct - ir:ir-batch6-6031	78	18:39:34 2013-06-17
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine - ir:309	101	02:24:55 2013-06-17
Isolation and characterization of carbene derivatives of LaC82(Cs) - ir:661	106	15:50:04 2013-06-18
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe technique - ir:ir-batch6-1362	73	01:17:32 2013-06-08
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique - ir:ir-batch6-1366	83	11:56:32 2013-06-13
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbene - ir:ir-batch6-1368	70	11:47:10 2013-06-13
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridine - ir:ir-batch6-1369	98	06:26:11 2013-06-19
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates - ir:ir-batch6-1371	87	08:45:46 2013-06-14
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide - ir:ir-batch6-1373	70	11:08:00 2013-06-19
Kinetic and spectroscopic properties of carbene-diazirine ylides - ir:ir-batch6-1376	79	13:55:06 2013-06-17
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenes - ir:ir-batch6-1378	87	01:17:53 2013-06-18
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirines - ir:ir-batch6-1379	67	00:03:00 2013-06-20
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopy - ir:ir-batch6-1381	73	00:39:41 2013-06-17
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systems - ir:ir-batch6-1382	74	22:57:45 2013-06-15
Gas phase protonation of diazirines - ir:ir-batch6-1383	68	05:03:48 2013-06-18
Benzylchlorocarbene - ir:ir-batch6-1385	83	09:00:59 2013-05-30
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical study - ir:ir-batch6-1386	94	03:18:08 2013-06-18
1, 2-H shift in benzylchlorocarbene - ir:ir-batch6-1390	77	18:18:19 2013-06-17
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysis - ir:ir-batch6-1391	77	04:02:32 2013-06-19
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a Carbene - ir:ir-batch6-1392	82	05:31:23 2013-06-20
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol - ir:ir-batch6-1393	73	17:53:39 2013-06-18
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullerene - ir:ir-batch6-1394	67	02:34:02 2013-06-20
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirine - ir:ir-batch6-1395	74	00:35:14 2013-06-20
Thermolysis and photolysis of arylchlorodiazirines in allyl bromide - ir:ir-batch6-1396	85	05:16:58 2013-06-20
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirine - ir:ir-batch6-1397	85	06:27:22 2013-06-19
Rearrangement of an ammonium ylide: mechanisms and kinetic parameters - ir:ir-batch6-1398	73	19:05:09 2013-06-19
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridine - ir:ir-batch6-1399	73	02:12:33 2013-06-20
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene - ir:ir-batch6-1400	81	10:41:43 2013-06-19
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixes - ir:ir-batch6-1401	74	18:41:43 2013-06-18
Cycloaddition of arylchlorocarbenes using ultrasound - ir:ir-batch6-1402	68	04:49:16 2013-06-20
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysis - ir:ir-batch6-1403	69	18:23:55 2013-06-18
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbene - ir:ir-batch6-1404	74	08:54:40 2013-06-14
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenes - ir:ir-batch6-1405	70	09:39:40 2013-06-14
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirine - ir:ir-batch6-1406	92	10:11:58 2013-06-19
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine - ir:ir-batch6-1407	111	05:49:08 2013-06-19
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene - ir:ir-batch6-1408	93	00:50:24 2013-06-19
Carboxylation of carbenes in low-temperature matrixes - ir:ir-batch6-1409	76	08:47:52 2013-06-14
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and amines - ir:ir-batch6-1410	76	17:23:33 2013-06-19
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-1411	89	08:43:01 2013-06-14
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbene - ir:ir-batch6-1412	91	15:59:33 2013-06-14
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formation - ir:ir-batch6-1413	87	11:55:51 2013-06-18
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene - ir:ir-batch6-1414	79	22:21:46 2013-06-16
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygen - ir:ir-batch6-1415	71	22:45:51 2013-06-15
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acid - ir:ir-batch6-1417	82	23:36:24 2013-06-18
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenes - ir:ir-batch6-1418	69	08:53:40 2013-06-14
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloaddition - ir:ir-batch6-1419	65	00:33:11 2013-06-17
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopy - ir:ir-batch6-1420	75	03:16:54 2013-06-17
Rates for 1, 2-migration in alkylchlorocarbenes - ir:ir-batch6-1421	92	12:05:22 2013-06-09
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes - ir:ir-batch6-1422	72	18:58:21 2013-06-19
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-1423	69	10:59:32 2013-06-19
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlation - ir:ir-batch6-1424	76	13:08:53 2013-06-19
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity - ir:ir-batch6-1425	64	09:02:53 2013-06-14
Spectroscopy and dynamics of para-nitrophenylchlorocarbene - ir:ir-batch6-1426	72	00:49:05 2013-06-19
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins - ir:ir-batch6-1427	71	07:39:52 2013-06-18
The barrier for 1, 2-hydrogen shift in dialkyl carbenes - ir:ir-batch6-1428	72	06:02:56 2013-06-18
Benzylchlorocarbene: a new ambiphile - ir:ir-batch6-1429	68	05:00:46 2013-06-18
Studies on benzylchlorocarbene - ir:ir-batch6-1430	71	17:38:33 2013-06-19
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene - ir:ir-batch6-1431	81	02:59:43 2013-06-17
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities - ir:ir-batch6-1432	87	17:35:23 2013-06-18
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis - ir:ir-batch6-1433	73	23:38:25 2013-06-19
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirine - ir:ir-batch6-1434	65	07:12:47 2013-06-19
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanol - ir:ir-batch6-1435	69	03:30:36 2013-06-19
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formation - ir:ir-batch6-1436	93	14:01:19 2013-06-19
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complex - ir:ir-batch6-1437	72	14:08:44 2013-06-17
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrile - ir:ir-batch6-1438	88	19:38:02 2013-06-19
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate - ir:ir-batch6-1439	76	09:09:55 2013-06-14
Catalysis of olefin isomerization by tight ion pairs - ir:ir-batch6-1440	64	01:23:12 2013-06-18
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetone - ir:ir-batch6-1441	82	20:06:52 2013-06-18
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate - ir:ir-batch6-1442	81	11:06:08 2013-06-19
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcohol - ir:ir-batch6-1443	73	18:31:47 2013-06-19
Electron spin resonance studies of diazirine anion radicals - ir:ir-batch6-1444	79	08:45:39 2013-06-14
Reaction of phenylchlorocarbene in oxygen-doped matrices - ir:ir-batch6-1445	70	07:51:48 2013-06-20
on the thermal decomposition of diazirines - ir:ir-batch6-1446	76	15:42:09 2013-06-18
Energy barrier for 1,2-hydrogen migration in benzylbromocarbene - ir:ir-batch6-1447	84	22:30:56 2013-06-15
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolane - ir:ir-batch6-1448	71	00:05:45 2013-06-20
Reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-1449	81	04:44:52 2013-06-19
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-1450	70	09:08:28 2013-06-14
Kinetics of the oxidation of cyclohexene by thallium(II1) acetate - ir:ir-batch6-1451	65	17:57:14 2013-06-14
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reaction - ir:ir-batch6-1452	85	09:09:38 2013-06-14
The order of CH3CHO decomposition - comment - ir:ir-batch6-1453	74	14:26:13 2013-06-19
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanol - ir:ir-batch6-1454	98	07:20:00 2013-06-20
Termolecular trapping of benzylchlorocarbene by methanol - ir:ir-batch6-1455	74	16:55:53 2013-06-19
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenes - ir:ir-batch6-1456	71	21:08:45 2013-06-19
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirine - ir:ir-batch6-1457	73	11:58:58 2013-06-19
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkene - ir:ir-batch6-1458	87	23:45:28 2013-06-12
Electronic effect on 1,2-hydrogen shift in chlorocarbenes - ir:ir-batch6-1459	77	21:52:13 2013-06-19
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylidene - ir:ir-batch6-1460	69	03:31:52 2013-06-18
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxide - ir:ir-batch6-1461	74	10:53:22 2013-06-19
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acid - ir:ir-batch6-1462	89	06:21:04 2013-06-18
Hydrogen bonding in alcohols: its effect on the carbene insertion reaction - ir:ir-batch6-1463	81	11:52:43 2013-06-19
The thermolysis and photolysis of diazirines - ir:ir-batch6-1464	66	04:11:18 2013-06-18
Dihydrosilaanthracenylidene and dihydroanthracenylidene - ir:ir-batch6-1465	78	20:14:38 2013-06-18
Electrochemical behavior of diazirines - ir:ir-batch6-1466	80	09:07:21 2013-06-14
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazene - ir:ir-batch6-1467	100	21:34:55 2013-06-18
Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimine - ir:ir-batch6-1468	86	14:09:08 2013-06-17
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirine - ir:ir-batch6-1469	72	08:55:23 2013-06-14
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impact - ir:ir-batch6-1470	81	07:08:51 2013-06-18
Synthesis of 3-chloro-3-methyl-d3-diazirine - ir:ir-batch6-1471	69	02:37:21 2013-06-17
MNDO calculations on diazirines - ir:ir-batch6-1472	99	11:08:56 2013-06-19
Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms - ir:ir-batch6-1473	70	09:11:33 2013-06-14
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decomposition - ir:ir-batch6-1474	73	01:45:40 2013-06-20
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathways - ir:ir-batch6-1475	71	11:54:10 2013-06-19
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes - ir:ir-batch6-1387	71	16:08:03 2013-06-17
Rearrangement of alkylchlorocarbenes - ir:ir-batch6-1389	65	20:25:00 2013-06-18
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridyl - ir:ir-batch6-1365	73	20:21:17 2013-06-19
Metal Atoms Collinear with the Spiro Carbon of 6,6-Open Adducts, M2@C80(Ad) (M = La and Ce, Ad = Adamantylidene) - ir:ir-batch6-6032	81	07:19:49 2013-06-18
Effect of substituents on the thermal decomposition of diazirines - ir:ir-batch6-1370	70	22:23:44 2013-06-14
Adamantylidene revisited - ir:ir-batch6-1384	79	16:50:50 2013-06-19
Nanorods of endohedral metallofullerene derivative - ir:662	101	15:50:14 2013-06-18
Photochemical decomposition of pyrazoline produced in the reaction of C60 with Diazoadamantane - ir:ir-batch6-1485	78	09:28:20 2013-06-19
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirine - ir:ir-batch6-5546	77	20:21:06 2013-06-19
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis - ir:ir-batch6-1416	120	10:06:49 2013-06-18

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