Michael Liu

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Details

NameMichael T. H. Liu
PositionEmeritus Faculty
Emailliu@upei.ca
Department(s)Chemistry
Phone(902) 566-0314
Websitehttp://research.upei.ca/profile/michaelliu

Research Interests

  • Carbenes
  • 1,2-Hydrogen Migration
  • laser flash photolysis
  • azomethine ylide
  • 1,5-cylization, synthesis of biologically active nitrogen-containing heterocycles
  • C60 carbene adducts

Other Scholars in Chemistry

Citations

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TitleAuthor(s)
Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimineLiu, Michael T. H.; Ibata, T.
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirineWakahara, T.; Niino, Y.; Kato, T.; Maeda, Y.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazeneVaughan, K.; Liu, Michael T. H.
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridineBonneau, R.; Collado, D.; Liu, Michael T. H.
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenesRomashin, Y. N.; Liu, Michael T. H.; Ma, W.; Moss, R. A.
MNDO calculations on diazirinesBurkholder, D.; Jones, W. E.; Ling, K. W.; Wasson, J. S.; Liu, Michael T. H.
Rates for 1, 2-migration in alkylchlorocarbenesBonneau, R.; Liu, Michael T. H.; Rayez, M. T.
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirineKwiatkowski, W.; Bakshi, P. K.; Cameron, T. S.; Liu, Michael T. H.
Synthesis of 3-chloro-3-methyl-d3-diazirineLiu, Michael T. H.; Chishti, N. H.; Burkholder, C. D.; Jones, W. E.; Wasson, J. S.
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenesLiu, Michael T. H.; Bonneau, R.
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirineLiu, Michael T. H.; Chishti, N. H.; Tencer, M.; Tomioka, H.; Izawa, Y.
S-heterocyclic carbene with a disilane backboneNikawa, H.; Nakahodo, T.; Tsuchiya, T.; Wakahara, T.; Rahman, G. M. A.; Akasaka, T.; Maeda, Y.; Liu, Michael T. H.; Meguro, A.; Kyushin, S.; Matsumoto, H.; Mizorogi, N.; Nagase, S.
1,2-Hydrogen migration in carbenes and mimicking processesBonneau, R.; Liu, Michael T. H.
Electrochemical behavior of diazirinesElson, C. M.; Liu, Michael T. H.
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysisJackson, J. E.; Soundararajan, N.; Platz, M. S.; Liu, Michael T. H.
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complexLiu, Michael T. H.; Soundararajan, N.; Paike, N.; Subramanian, R.
Spectroscopy and dynamics of para-nitrophenylchlorocarbeneBonneau, R.; Liu, Michael T. H.
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetoneIbata, T.; Liu, Michael T. H.; Toyoda, J.
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullereneLiu, Michael T. H.; Romashin, Y. N.; Kubota, M.; Ohashi, M.
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adductAkasaka, Takeshi; Kono, Takayoshi; Takematsu, Yuji; Nikawa, Hidefumi; Nakahodo, Tsukasa; Wakahara, Takatsugu; Ishitsuka, Midori O.; Tsuchiya, Takahiro; Maeda, Yutaka; Liu, Michael T. H.; Yoza, Kenji; Kato, Tatsuhisa; Yamamoto, Kazunori; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirineLiu, Michael T. H.; Palmer, G. E.; Chishti, N. H.
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substratesRomashin, Y. N.; Liu, Michael T. H.; Hill, B. T.; Platz, M. S.
Hydrogen bonding in alcohols: its effect on the carbene insertion reactionGriller, D.; Liu, Michael T. H.; Scaiano, J. C.
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and aminesBonneau, R.; Liu, Michael T. H.
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygenLiu, Michael T. H.; Bonneau, R.; Jefford, C. W.
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicityBonneau, R.; Liu, Michael T. H.; Suresh, R. V.
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acidStevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
Reaction of benzylchlorocarbene with hydrogen chlorideLiu, Michael T. H.; Subramanian, R.
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkeneTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Benzylchlorocarbene: a new ambiphileLiu, Michael T. H.; Suresh, R. V.; Soundararajan, N.; Vessey, E. G.
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine Cameron, T. S.; Bakshi, P. K.; Borecka, B.; Liu, Michael T. H.
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleateDoyle, M. P.; Loh, K. L.; Nishioka, L. I.; Mcvickar, M. B.; Liu, Michael T. H.
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene)Yamada, M.; Someya, C.; Wakahara, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenesTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbeneChateauneuf, J. E.; Liu, Michael T. H.
Energy barrier for 1,2-hydrogen migration in benzylbromocarbeneLiu, Michael T. H.; Subramanian, R.
Photolysis of diazirines in the presence of C-60Akasaka, T.; Liu, Michael T. H.; Niino, Y.; Maeda, Y.; Wakahara, T.; Okamura, M.; Kobayashi, K.; Nagase, S.
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirineLiu, Michael T. H.; Chateauneuf, J. E.
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanolTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirinesShustov, G. V.; Liu, Michael T. H.; Houk, K. N.
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impactLiu, Michael T. H.; Tanaka, T.; Hirotsu, T.; Fukui, K.; Fujita, I.; Kuwata, K.
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrileLiu, Michael T. H.; Paike, N.
1, 2-H shift in benzylchlorocarbene Liu, Michael T. H.; Bonneau, R.; Wierlacher, S.; Sander, W.
BenzylchlorocarbeneMerrer, D. C.; Moss, R. A.; Liu, Michael T. H.; Banks, J. T.; Ingold, K. U.
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe techniqueIshitsuka, M. O.; Niino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcoholLiu, Michael T. H.; Subramanian, R.
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbeneLiu, Michael T. H.
Thermolysis and photolysis of arylchlorodiazirines in allyl bromideBonneau, R.; Grobys, M.; Liu, Michael T. H.; Himori, M.; Fukushima, K.; Ibata, T.
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirineLiu, Michael T. H.; Bonneau, R.
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbeneBonneau, R.; Collado, D.; Dalibart, M.; Liu, Michael T. H.
Structural determination of metallofuIlerene SC3C82 revisitedLiduka, Y.; Wakahara, T.; Nakahodo, T.; Tsuchiya, T.; Sakuraba, A.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Kato, T.; Liu, Michael T. H.; Mizorogi, N.; Kobayashi, K.; Nagase, S.
Dihydrosilaanthracenylidene and dihydroanthracenylideneSekiguchi, A.; Ando, W.; Sugawara, T.; Iwamura, H.; Liu, Michael T. H.
Adamantylidene revisitedBonneau, R.; Hellrung, B.; Liu, Michael T. H.; Wirz, J.
Studies on benzylchlorocarbeneLiu, Michael T. H.; Suresh, R. V.
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systemsShustov, G. V.; Liu, Michael T. H.
Catalysis of olefin isomerization by tight ion pairsLiu, Michael T. H.; Doyle, M. P.; Loh, K. L.; Anand, S. M.
Reaction of 3-chloro-3-methyldiazirines with hydrogen atomsBurkholder, C. D.; Jones, W. E.; Wasson, J. S.; Liu, Michael T. H.
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefinsJackson, J. E.; Soundararajan, N.; Platz, M. S.; Doyle, M. P.; Liu, Michael T. H.
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acidGriller, D.; Liu, Michael T. H.; Montgomery, C. R.; Scaiano, J. C.; Wong, P. C.
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlationBonneau, R.; Liu, Michael T. H.; Lapouvade, R.
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxideSugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
The order of CH3CHO decomposition - commentLiu, Michael T. H.
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reactionLiu, Michael T. H.; Subramanian, R.
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulideRomashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridylBonneau, R.; Liu, Michael T. H.
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atomsRomashin, Y. N.; Liu, Michael T. H.; Nijjar, S. S.; Attanasi, O. A.
Reaction of phenylchlorocarbene in oxygen-doped matricesGanzer, G. A.; Sheridan, R. S.; Liu, Michael T. H.
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloadditionBonneau, R.; Liu, Michael T. H.
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenesLiu, Michael T. H.; Bonneau, R.
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienesRomashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirineIshitsuka, Midori O.; Enoki, Haruka; Tsuchiya, Takahiro; Slanina, Zdenek; Mizorogi, Naomi; Nagase, Shigeru; Liu, Michael T. H.; Akasaka, Takeshi
Cycloaddition of arylchlorocarbenes using ultrasoundBertram, A. K.; Liu, Michael T. H.
Gas phase protonation of diazirinesMatsumoto, T.; Kobayashi, S.; Mishima, M.; Shustov, G. V.; Liu, Michael T. H.
Carboxylation of carbenes in low-temperature matrixesWierlacher, S.; Sander, W.; Liu, Michael T. H.
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarateLiu, Michael T. H.; Soundararajan, N.; Anand, S. M.; Ibata, T.
Rearrangement of alkylchlorocarbenesBonneau, R.; Liu, Michael T. H.; Kim, K. C.; Goodman, J. L.
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanolLiu, Michael T. H.; Subramanian, R.
Isolation and characterization of carbene derivatives of LaC82(Cs)Akasaka, Takeshi; Kono, Takayoshi; Matsunaga, Yoichiro; Wakahara, Takatsugu; Nakahodo, Tsukasa; Ishitsuka, Midori; Maeda, Yutaka; Tsuchiya, Takahiro; Kato, Tatsuhias; Liu, Michael T.H.; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a CarbeneLiu, Michael T. H.
Effect of substituents on the thermal decomposition of diazirinesLiu, Michael T. H.; Choe, Y. K.; Kimura, M.; Kobayashi, K.; Nagase, S.; Wakahara, T.; Niino, Y.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbeneLiu, Michael T. H.; Chapman, R. G.; Bonneau, R.
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe techniqueIshitsuka, M. O.; Enoki, H.; Nikawa, H.; Wakahara, T.; Tsuchiya, T.; Akasaka, T.; Liu, Michael T. H.
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenesLiu, Michael T. H.; Bonneau, R.
Rearrangement of an ammonium ylide: mechanisms and kinetic parametersBonneau, R.; Reuter, I.; Liu, Michael T. H.
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formationChateauneuf, J. E.; Liu, Michael T. H.
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienesBonneau, R.; Romashin, Y. N.; Liu, Michael T. H.
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decompositionLoucks, L. F.; Liu, Michael T. H.; Hooper, D. G.
Quantum yield of formation of diazo compounds from the photolysis of diazirinesBonneau, R.; Liu, Michael T. H.
Nanorods of endohedral metallofullerene derivativeTsuchiya, Takahiro; Kumashiro, Ryotaro; Tanigaki, Katsumi; Matsunaga, Yoichiro; Ishitsuka, Midori O.; Wakahara, Takatsugu; Maeda, Yutaka; Takano, Yuta; Aoyagi, Motoki; Akasaka, Takeshi; Liu, Michael T. H.; Kato, Tatsuhisa; Suenaga, Kazutomo; Jeong, Jong S.; Iijima, Sumio; Kimura, Fumiko; Kimura, Tsunehisa; Nagasev, Shigeru
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixesWierlacher, S.; Sander, W.; Liu, Michael T. H.
The thermolysis and photolysis of diazirines Liu, Michael T. H.
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbeneDoyle, M. P.; Taunton, J.; Oon, S. M.; Liu, Michael T. H.; Soundararajan, N.; Platz, M. S.; Jackson, J. E.
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbeneLiu, Michael T. H.
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolaneLiu, Michael T. H.; Kokosi, J.
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylideneSugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathwaysLiu, Michael T. H.; Yamamoto, I.
on the thermal decomposition of diazirinesLiu, Michael T. H.; Tencer, M.; Stevens, I. D. R.
Electronic effect on 1,2-hydrogen shift in chlorocarbenesLiu, Michael T. H.; Tencer, M.
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirineLinden, A.; Cameron, T. S.; Liu, Michael T. H.; Anand, S. M.
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbeneLiu, Michael T. H.; Murray, S.; Zhu, J. H.
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivitiesSoundararajan, N.; Platz, M. S.; Jackson, J. E.; Doyle, M. P.; Oon, S. M.; Liu, Michael T. H.; Anand, S. M.
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysisBonneau, R.; Liu, Michael T. H.
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formationIbata, T.; Toyoda, J.; Liu, Michael T. H.
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivativeIiduka, Y.; Wakahara, T.; Nakajima, K.; Nakahodo, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopyLiu, Michael T. H.; Bonneau, R.
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcoholLiu, Michael T. H.; Romashin, Y. N.; Venkatachalam, T. K.
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbeneJackson, J. E.; Soundararajan, N.; White, W.; Liu, Michael T. H.; Bonneau, R.; Platz, M. S.
The barrier for 1, 2-hydrogen shift in dialkyl carbenesStevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
Termolecular trapping of benzylchlorocarbene by methanolLiu, Michael T. H.; Subramanian, R.
Kinetic and spectroscopic properties of carbene-diazirine ylidesBonneau, R.; Liu, Michael T. H.
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenesLiu, Michael T. H.; Bonneau, R.
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridineBonneau, R.; Romashin, Y. N.; Liu, Michael T. H.; Macpherson, S. E.
Photochemical decomposition of pyrazoline produced in the reaction of C60 with DiazoadamantaneNiino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical studyShustov, G. V.; Liu, Michael T. H.; Rauk, A.
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopyWerstiuk, N. H.; Muchall, H. M.; Ma, J. G.; Liu, Michael T. H.
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirineLiu, Michael T. H.
Isolation and characterization of a carbene derivative of La@C-82Maeda, Y.; Matsunaga, Y.; Wakahara, T.; Takahashi, S.; Tsuchiya, T.; Ishitsuka, M. O.; Hasegawa, T.; Akasaka, T.; Liu, Michael T. H.; Kokura, K.; Horn, E.; Yoza, K.; Kato, T.; Okubo, S.; Kobayashi, K.; Nagase, S.; Yamamoto, K.
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbeneLiu, Michael T. H.; Chateauneuf, J. E.
Electron spin resonance studies of diazirine anion radicalsElson, C. M.; Liu, Michael T. H.; Mailer, C.
Kinetics of the oxidation of cyclohexene by thallium(II1) acetateLoucks, L. F.; Liu, Michael T. H.; Durant, D. K.
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysisLiu, Michael T. H.; Romashin, Y. N.; Bonneau, R.
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chlorideLiu, Michael T. H.; Chateauneuf, J. E.
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysisBonneau, R.; Liu, Michael T. H.; Subramanian, R.; Linkletter, Barry A.; Stevens, I. D. R.

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Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimine - ir:ir-batch6-146828714:56:19 2015-05-25
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine - ir:ir-batch6-137231005:15:46 2015-05-22
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazene - ir:ir-batch6-146733414:23:43 2015-05-23
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridine - ir:ir-batch6-136931223:53:25 2015-05-22
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenes - ir:ir-batch6-137829117:26:21 2015-05-25
MNDO calculations on diazirines - ir:ir-batch6-147231808:35:33 2015-05-17
Rates for 1, 2-migration in alkylchlorocarbenes - ir:ir-batch6-142131002:50:56 2015-05-26
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirine - ir:ir-batch6-139529400:47:53 2015-05-23
Synthesis of 3-chloro-3-methyl-d3-diazirine - ir:ir-batch6-147129311:02:53 2015-05-24
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenes - ir:ir-batch6-141830506:55:40 2015-05-25
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirine - ir:ir-batch6-145729212:49:42 2015-05-23
S-heterocyclic carbene with a disilane backbone - ir:ir-batch6-136330016:53:35 2015-05-24
1,2-Hydrogen migration in carbenes and mimicking processes - ir:ir-batch6-148631915:11:06 2015-05-25
Electrochemical behavior of diazirines - ir:ir-batch6-146633605:46:32 2015-05-23
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis - ir:ir-batch6-143329402:53:19 2015-05-25
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complex - ir:ir-batch6-143728711:02:37 2015-05-23
Spectroscopy and dynamics of para-nitrophenylchlorocarbene - ir:ir-batch6-142630321:39:59 2015-05-22
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetone - ir:ir-batch6-144129323:51:16 2015-05-24
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullerene - ir:ir-batch6-139428112:57:32 2015-05-24
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adduct - ir:ir-batch6-603132713:45:00 2015-05-25
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirine - ir:ir-batch6-146927605:30:34 2015-05-17
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates - ir:ir-batch6-137134110:50:16 2015-05-25
Hydrogen bonding in alcohols: its effect on the carbene insertion reaction - ir:ir-batch6-146325811:53:47 2015-05-16
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and amines - ir:ir-batch6-141028519:12:21 2015-05-22
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygen - ir:ir-batch6-141527823:17:54 2015-05-25
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity - ir:ir-batch6-142527908:50:02 2015-05-23
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acid - ir:ir-batch6-141730808:36:50 2015-05-23
Reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-144929015:09:03 2015-05-23
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkene - ir:ir-batch6-145830523:06:38 2015-05-25
Benzylchlorocarbene: a new ambiphile - ir:ir-batch6-142927812:35:35 2015-05-25
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine - ir:ir-batch6-140737714:17:22 2015-05-25
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate - ir:ir-batch6-144229820:27:07 2015-05-25
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene) - ir:ir-batch6-603230008:45:41 2015-05-22
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenes - ir:ir-batch6-145626418:30:33 2015-05-25
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbene - ir:ir-batch6-141230111:19:12 2015-05-25
Energy barrier for 1,2-hydrogen migration in benzylbromocarbene - ir:ir-batch6-144730704:16:55 2015-05-23
Photolysis of diazirines in the presence of C-60 - ir:ir-batch6-137428902:00:58 2015-05-24
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirine - ir:ir-batch6-139727501:23:32 2015-05-26
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanol - ir:ir-batch6-145431308:50:00 2015-05-22
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirines - ir:ir-batch6-137926914:25:54 2015-05-25
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impact - ir:ir-batch6-147028805:48:23 2015-05-23
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrile - ir:ir-batch6-143831714:31:55 2015-05-24
1, 2-H shift in benzylchlorocarbene - ir:ir-batch6-139028600:00:57 2015-05-23
Benzylchlorocarbene - ir:ir-batch6-138529900:32:01 2015-05-23
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique - ir:ir-batch6-136631119:01:19 2015-05-24
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcohol - ir:ir-batch6-144326920:52:31 2015-05-25
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-145025301:30:15 2015-05-24
Thermolysis and photolysis of arylchlorodiazirines in allyl bromide - ir:ir-batch6-139632300:38:45 2015-05-23
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirine - ir:ir-batch6-140628708:40:45 2015-05-23
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbene - ir:ir-batch6-136826006:31:59 2015-05-24
Structural determination of metallofuIlerene SC3C82 revisited - ir:ir-batch6-136430511:27:23 2015-05-25
Dihydrosilaanthracenylidene and dihydroanthracenylidene - ir:ir-batch6-146527114:25:04 2015-05-25
Adamantylidene revisited - ir:ir-batch6-138429306:49:52 2015-05-25
Studies on benzylchlorocarbene - ir:ir-batch6-143028212:50:23 2015-05-23
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systems - ir:ir-batch6-138227923:29:27 2015-05-25
Catalysis of olefin isomerization by tight ion pairs - ir:ir-batch6-144024222:55:00 2015-05-25
Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms - ir:ir-batch6-147324608:32:57 2015-05-25
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins - ir:ir-batch6-142726708:51:59 2015-05-23
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acid - ir:ir-batch6-146231103:11:59 2015-05-19
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlation - ir:ir-batch6-142428012:07:10 2015-05-23
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxide - ir:ir-batch6-146126315:09:54 2015-05-22
The order of CH3CHO decomposition - comment - ir:ir-batch6-145330009:25:11 2015-05-23
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reaction - ir:ir-batch6-145227404:52:31 2015-05-23
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide - ir:ir-batch6-137324912:41:29 2015-05-25
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridyl - ir:ir-batch6-136528003:10:25 2015-05-26
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atoms - ir:ir-batch6-137529716:25:38 2015-05-24
Reaction of phenylchlorocarbene in oxygen-doped matrices - ir:ir-batch6-144528320:56:56 2015-05-22
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloaddition - ir:ir-batch6-141925919:24:03 2015-05-16
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes - ir:ir-batch6-142229514:01:26 2015-05-16
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienes - ir:ir-batch6-138031523:06:43 2015-05-22
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine - ir:30935422:59:15 2015-05-16
Cycloaddition of arylchlorocarbenes using ultrasound - ir:ir-batch6-140226609:07:38 2015-05-14
Gas phase protonation of diazirines - ir:ir-batch6-138325712:38:37 2015-05-23
Carboxylation of carbenes in low-temperature matrixes - ir:ir-batch6-140928508:38:48 2015-05-23
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate - ir:ir-batch6-143929802:05:53 2015-05-17
Rearrangement of alkylchlorocarbenes - ir:ir-batch6-138927016:19:18 2015-05-16
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanol - ir:ir-batch6-143524908:59:19 2015-05-23
Isolation and characterization of carbene derivatives of LaC82(Cs) - ir:66137011:40:07 2015-05-19
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a Carbene - ir:ir-batch6-139230506:14:35 2015-05-22
Effect of substituents on the thermal decomposition of diazirines - ir:ir-batch6-137025716:27:00 2015-05-23
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene - ir:ir-batch6-140829016:26:33 2015-05-25
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe technique - ir:ir-batch6-136227823:50:33 2015-05-22
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenes - ir:ir-batch6-140527614:44:53 2015-05-25
Rearrangement of an ammonium ylide: mechanisms and kinetic parameters - ir:ir-batch6-139826518:59:39 2015-05-25
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formation - ir:ir-batch6-141332523:55:48 2015-05-25
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienes - ir:ir-batch6-137731202:08:30 2015-05-20
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decomposition - ir:ir-batch6-147425613:01:38 2015-05-25
Quantum yield of formation of diazo compounds from the photolysis of diazirines - ir:ir-batch6-138829909:31:56 2015-05-23
Nanorods of endohedral metallofullerene derivative - ir:66235021:57:47 2015-05-22
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixes - ir:ir-batch6-140127714:54:41 2015-05-12
The thermolysis and photolysis of diazirines - ir:ir-batch6-146424021:26:48 2015-05-25
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene - ir:ir-batch6-143128811:11:17 2015-05-23
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene - ir:ir-batch6-140029103:41:53 2015-05-16
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolane - ir:ir-batch6-144826423:20:25 2015-05-22
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylidene - ir:ir-batch6-146026020:53:10 2015-05-22
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathways - ir:ir-batch6-147527618:14:39 2015-05-22
on the thermal decomposition of diazirines - ir:ir-batch6-144628022:00:52 2015-05-24
Electronic effect on 1,2-hydrogen shift in chlorocarbenes - ir:ir-batch6-145926619:04:43 2015-05-24
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirine - ir:ir-batch6-143424614:52:33 2015-05-25
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene - ir:ir-batch6-141427213:49:14 2015-05-14
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities - ir:ir-batch6-143231610:54:11 2015-05-14
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysis - ir:ir-batch6-140326708:43:42 2015-05-23
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formation - ir:ir-batch6-143633203:10:31 2015-05-23
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivative - ir:ir-batch6-554731908:55:07 2015-05-24
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopy - ir:ir-batch6-142028102:53:04 2015-05-26
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol - ir:ir-batch6-139327700:36:10 2015-05-23
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-142329611:03:12 2015-05-23
The barrier for 1, 2-hydrogen shift in dialkyl carbenes - ir:ir-batch6-142827202:58:43 2015-05-25
Termolecular trapping of benzylchlorocarbene by methanol - ir:ir-batch6-145526702:55:19 2015-05-26
Kinetic and spectroscopic properties of carbene-diazirine ylides - ir:ir-batch6-137628318:47:59 2015-05-24
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes - ir:ir-batch6-138725021:42:49 2015-05-20
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridine - ir:ir-batch6-139925903:23:28 2015-05-26
Photochemical decomposition of pyrazoline produced in the reaction of C60 with Diazoadamantane - ir:ir-batch6-148527203:02:42 2015-05-24
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical study - ir:ir-batch6-138630409:11:13 2015-05-23
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopy - ir:ir-batch6-138128300:44:10 2015-05-26
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirine - ir:ir-batch6-554627420:30:59 2015-05-25
Isolation and characterization of a carbene derivative of La@C-82 - ir:ir-batch6-136727901:55:48 2015-05-26
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbene - ir:ir-batch6-140427705:10:33 2015-05-23
Electron spin resonance studies of diazirine anion radicals - ir:ir-batch6-144427314:24:12 2015-05-25
Kinetics of the oxidation of cyclohexene by thallium(II1) acetate - ir:ir-batch6-145124813:48:36 2015-05-23
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysis - ir:ir-batch6-139128414:36:56 2015-05-25
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-141130613:04:33 2015-05-24
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis - ir:ir-batch6-141654608:11:07 2015-05-23