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Carboxylation of carbenes in low-temperature matrixes

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Spectroscopic detection of ammonium ylides from arylchlorocarbenes and amines

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Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chloride

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The rate constant for the reaction of benzylchlorocarbene with HCl is 4.7 x 10(9) dm3 mol-1 s-1.

Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbene

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Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formation

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Laser flash photolysis of 3-chloro-3-(p-nitrophenyl)diazirine (1) generates the corresponding ground-state singlet carbene (lambda-max = 310 nm), which reacts with ethyl acetate to form a carbonyl ylide of the ester (lambda-max = 490 nm). The absolute rate constant for ylide formation in CH2Cl2 is k...

Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene

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Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygen

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The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acid

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Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenes

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A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloaddition

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Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopy

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Rates for 1, 2-migration in alkylchlorocarbenes

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Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes

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Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene

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Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlation

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Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity

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Spectroscopy and dynamics of para-nitrophenylchlorocarbene

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Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins

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The barrier for 1, 2-hydrogen shift in dialkyl carbenes

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Benzylchlorocarbene: a new ambiphile

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Studies on benzylchlorocarbene

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Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene

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Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities

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Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis

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Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirine

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